Model for the correction of the specific gravity of biodiesel from residual oil
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Abstract
Biodiesel is a important fuel with economic benefits, social and environmental. The production cost of the biodiesel can be significantly lowered if the raw material is replaced by a alternative material as residual oil. In this study, the variation of specific gravity with temperature increase for diesel and biodiesel from residual oil obtained by homogeneous basic catalysis. All properties analyzed for biodiesel are within specification Brazil. The determination of the correction algorithm for the specific gravity function of temperature is also presented, and the slope of the line to diesel fuel, methylic biodiesel (BMR) and ethylic biodiesel (BER) from residual oil were respectively the values -0.7089, -0.7290 and -0.7277. This demonstrates the existence of difference of the model when compared chemically different fuels, like diesel and biodiesel from different sources, indicating the importance of determining the specific algorithm for the operations of conversion of volume to the reference temperature.
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References
ANP. (2012) Sítio da Agência Nacional de Petróleo, Gás Natural e Biocombustíveis - ANP. Resolução nº 7, de 19 de março de 2008.
ABU-JRAI, A.; RODRÍGUEZ-FERNÁNDEZ, J.; TSOLAKIS, A.; MEGARITIS, A.; THEINNOI, K.; CRACKNELL, R. F.; CLARK, R. H. (2009) Performance, combustion and emissions of a diesel engine operated with reformed EGR. Comparison of diesel and GTL fuelling. Fuel, n. 88, p. 1031-1041.
ALPTEKIN, E.; CANAKCI, M. (2008) Determination of the density and the viscosities of biodiesel-diesel fuel blends. Renewable Energy, n. 33, p. 2623-2630.
ALTUN, S.; BULUT, H.; ÖNER, C. (2008) The comparison of engine performance and exhaust emission characteristics of sesame oil-diesel fuel mixture with diesel fuel in a direct injection diesel engine. Renewable Energy, n. 33, p. 1791-1795.
ATADASHI, I. M.; AROUA, M. K.; AZIZ, A. A. (2010) High quality biodiesel and its diesel engine application: A review. Renewable and Sustainable Energy Reviews, n. 14, p. 1999-2008.
BALAT, M.; BALAT, H. (2010) Progress in biodiesel processing. Applied Energy, n. 87, p. 1815-1835.
CASTRO, M. P. P.; ANDRADE, A. A.; FRANCO, R. W. A.; MIRANDA, P. C. M. L.; STHEL, M.; VARGAS, H.; CONSTANTINO, R.; BAESSO, M. L. (2005) Thermal properties measurements in biodiesel oils using photothermal techniques. Chemical Physics Letters, n. 411, p. 18-22.
DABDOUB, M.; BRONZEL, J.; RAMPIM, M. (2009) Biodiesel: visão crítica do status atual e perspectivas na academia e na indústria. Química Nova, n. 32, p. 776-779.
DANTAS, M. B.; ALBUQUERQUE, A. R.; BARROS FILHO, A. K.; RODRIGUES FILHO, M. G.; ANTONIOSI FILHO, N. R.; SINFRÔNIO, F. S. M.; ROSENHAIM, R.; SOLEDADE, L. E. B.; SANTOS, I. M. G.; SOUZA, A. G. (2011) Evaluation of the oxidative stability of corn biodiesel. Fuel, n. 90, p. 773-778.
DEMIRBAS, A. (2009) Political, economic and environmental impacts of biofuels: A review. Applied Energy, n. 86, p. S108-S117.
ENCINAR, J. M.; SÁNCHEZ, N.; MARTÍNEZ, G.; GARCÍA, L. (2011) Study of biodiesel production from animal fats with high free fatty acid content. Bioresource Technology, n. 102, p. 10907-10914.
HAAS, M. J.; MCALOON, A. J.; YEE, W. C.; FOGLIA, T. A. (2006) A process model to estimate biodiesel production costs. Bioresource Technology, n. 97, p. 671-678.
HOEKMAN, S. K.; BROCH, A.; ROBBINS, C.; CENICEROS, E.; NATARAJAN, M. (2011) Review of biodiesel composition, properties, and specifications. Renewable and Sustainable Energy Reviews, n. 16, p. 143-169.
JORGE, N.; SOARES, B. B. P.; LUNARDI, V. M.; MALACRIDA, C. R. (2005) Alterações físico-químicas dos óleos de girassol, milho e soja em frituras. Química Nova, n. 28, p. 947-951.
KNOTHE, G. (2005) Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters. Fuel Processing Technology, n. 86, p. 1059-1070.
KNOTHE, G. (2007) Some aspects of biodiesel oxidative stability. Fuel Processing Technology, n. 88, p. 669-677.
LAM, M. K.; LEE, K. T.; MOHAMED, A. R. (2010) Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: A review. Biotechnology Advances, n. 28, p. 500-518.
MONTGOMERY, D. C. (2001) Design and Analyses of Experiments, New York, Wiley.
MORÓN-VILLARREYES, J. A.; SOLDI, C.; DE AMORIM, A. M.; PIZZOLATTI, M. G.; DE MENDONÇA JR, A. P.; D'OCA, M. G. M. (2007) Diesel/biodiesel proportion for by-compression ignition engines. Fuel, n. 86, p. 1977-1982.
NAMASIVAYAM, A. M.; KORAKIANITIS, T.; CROOKES, R. J.; BOB-MANUEL, K. D. H.; OLSEN, J. (2010) Biodiesel, emulsified biodiesel and dimethyl ether as pilot fuels for natural gas fuelled engines. Applied Energy, n. 87, p. 769-778.
RODRÍGUEZ-ANTÓN, L. M.; APARICIO, C.; GUIGNON, B.; SANZ, P. D. (2008) Volumetric properties at high pressure of waste oil methyl ester compared with diesel oil. Fuel, n. 87, p. 1934-1940.
SANTOS, A. D. Q.; VIEIRA, D. F. (2010) Determinação de coeficiente de expansão térmica do biodiesel e seus impactos no sistema de medição volumétrico. Eclética Química, n. 35, p. 107-112.
SHARMA, Y. C.; SINGH, B.; UPADHYAY, S. N. (2008) Advancements in development and characterization of biodiesel: A review. Fuel, n. 87, p. 2355-2373.
SKOOG, D. A.; WEST, D. M.; HOLLER, J. F.; CROUCH, S. R. (2007) Fundamentos de Química Analítica. Tradução da 8ª ed. norte-americana, São Paulo, Editora Thomson
TAT, M.; VAN GERPEN, J. (2000) The specific gravity of biodiesel and its blends with diesel fuel. Journal of the American Oil Chemists Society, n. 77, p. 115-119.
VALENTE, O. S.; PASA, V. M. D.; BELCHIOR, C. R. P.; SODRÉ, J. R. (2011) Physical-chemical properties of waste cooking oil biodiesel and castor oil biodiesel blends. Fuel, n. 90, p. 1700-1702.
WANG, Y.; OU, P. L. S.; ZHANG, Z. (2007) Preparation of biodiesel from waste cooking oil via two-step catalyzed process. Energy Conversion and Management, n. 48, p. 184-188.
YOON, S. H. P.; PARK, S. H.; LEE, C. S. (2008) Experimental Investigation on the Fuel Properties of Biodiesel and Its Blends at Various Temperatures. Energy & Fuels, n. 22, p. 652–656.